Team Captain would be the one and only Lana Kane!! She gets the job done even when Archer screws up which shows just how amazing she is, not to mention how hot she is too.
1st Round Pick- Batman. His parents died and so did his personality, but in it's place, one of the greatest superheroes ever was born. He's human and he's kicked SuperMan's ass, doesn't get any better than that.
2nd Round Pick- Deadpool because we'll need someone to lighten the mood.
3rd Round Pick- Mewtwo. He's the original superior pokemon and a force to be reckon with.